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Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex: [K(DB18C6)]2[Pd(SCN)4] |
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| Authors: | Jian Min DOU Ying LIU Lan Ying ZHU De Zhi SUN Pei Ju ZHENG Chen Xia DU Yu ZHU |
| Abstract: | A novel Pd(II)-dibenzo-18-crown-6 (DB18C6) complex K(DB18C6)]2Pd(SCN)4] has been isolated and characterized by X-ray diffraction analysis. In the solid state, it displays a quasi-one-dimensional infinite chain of two K(DB18C6)] + complex cations and a Pd(SCN)4]2- anion bridged by K+-p interactions between adjacent K(DB18C6)] + units. |
| Keywords: | Cation-p interactions crown ether crystal structure palladium complex |
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