| Synthesis and characterization of quaternized poly（phthalazinone ether sulfone ketone） for anion-exchange membrane |
| |
| 作者姓名： | Xi Gao Jian Chun Yan Hua Min Zhang Shou Hai Zhang Cheng Liu Ping Zhao |
| |
| 作者单位： | [1]Department of Polymer Materials, Dalian University of Technology, Dalian 116012, China [2]PEMFC Key Materials ＆ Technology Laboratory, Dalian Institute of Chemical Physics （DICP）, Chinese Academy of Sciences, Dalian 116023, China |
| |
| 基金项目： | 国家重点基础研究发展计划(973计划);国家自然科学基金 |
| |
| 摘 要： | Chloromethylated poly(phthalazinone ether sulfone ketone) (CMPPESK) was prepared from poly(phthalazinone ether sulfone ketone) (PPESK) using chloromethyl octyl ethers (CMOE) with lower toxicity as chloromethylated regent.CMPPESK was soluble in N-methyl-2-pyrrolidone (NMP),N,N-dimethylacetamide (DMAc) and chloroform.Quatemized poly(phthalazinone ether sulfone ketone) (QAPPESK) was prepared from CMPPESK by quaternization.QAPPESK had excellent solvent resistance, which was only partly soluble in sulfuric acid (98%) and swollen in N,N-dimethylformamide (DMF).The vanadium redox flow battery (V-RFB) using QAPPESK anion-exchange membrane had better performance with 88.3% of overall energy efficiency.
|
| 关 键 词： | 氯甲基化作用 季铵化作用 砜 有机硫化合物 |
Synthesis and characterization of quaternized poly(phthalazinone ether sulfone ketone) for anion-exchange membrane |
| |
| Xi Gao Jian Chun Yan Hua Min Zhang Shou Hai Zhang Cheng Liu Ping Zhao.Synthesis and characterization of quaternized poly(phthalazinone ether sulfone ketone) for anion-exchange membrane[J].Chinese Chemical Letters,2007,18(10):1269-1272. |
| |
| Authors: | Xi Gao Jian Chun Yan Hua Min Zhang Shou Hai Zhang Cheng Liu Ping Zhao |
| |
| Institution: | 1. Department of Polymer Materials, Dalian University of Technology, Dalian 116012, China;2. PEMFC Key Materials & Technology Laboratory, Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences, Dalian 116023, China |
| |
| Abstract: | Chloromethylated poly(phthalazinone ether sulfone ketone) (CMPPESK) was prepared from poly(phthalazinone ether sulfone ketone) (PPESK) using chloromethyl octyl ethers (CMOE) with lower toxicity as chloromethylated regent.CMPPESK was soluble in N-methyl-2-pyrrolidone (NMP),N,N-dimethylacetamide (DMAc) and chloroform.Quatemized poly(phthalazinone ether sulfone ketone) (QAPPESK) was prepared from CMPPESK by quaternization.QAPPESK had excellent solvent resistance, which was only partly soluble in sulfuric acid (98%) and swollen in N,N-dimethylformamide (DMF).The vanadium redox flow battery (V-RFB) using QAPPESK anion-exchange membrane had better performance with 88.3% of overall energy efficiency. |
| |
| Keywords: | Chloromethylation Quaternization Poly(phthalazinone ether sulfone ketone) Anion-exchange membrane Vanadium redox flow battery |
| 本文献已被 维普 万方数据 ScienceDirect 等数据库收录！ |
