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An efficient method to synthesize HMX by nitrolysis of DPT with N_2O_5 and a novel ionic liquid |
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| Authors: | Hui Zhen Zhi Jun Luo Guang An Feng Chun Xu Lv School of Chemical Engineering Nanjing University of Science Technology Nanjing China |
| Institution: | School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China |
| Abstract: | A novel polyethylene glycol(PEG)-200-based dicationic acidic ionic liquid(PEG200-DAIL)was used to synthesize HMX from DPT by nitrolysis with N2O5.It was found that either N2O5 or PEG200-DAIL could improve the yield.Furthermore,the combined use of PEG200-DAIL and N2O5 could increase the yield of HMX to 64%with the used quantity of HNO3 decreased.dramatically |
| Keywords: | DPT Nitrolysis N2O5 Acidic ionic liquid |
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