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Desulfurization using the 1,2-dimethylimidazolium ionic liquid as an adsorbent
Authors:Yue-Qin Cai  Gong-Hua Song  Dian-Ni Liang
Institution:a School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China; b Shanghai Key Laboratory of Chemical Biology, Institute of Pesticides & Pharmaceuticals, East China University of Science and Technology, Shanghai 200237, China
Abstract:The aim of this study is to investigate the possible use of a 1,2-dimethylimidazolium ionic liquid, 2,2-bis((1,2-dimethylimidazolium)methyl)propane-1,3-diol hexafluorophosphate (1), as an adsorbent to selectively remove aromatic heterocyclic sulfur compounds from model fuels. The result indicates that adsorbent 1 is insoluble in model fuels. The spent IL saturated sulfur compounds could be regenerated by a water dilution process. The influence of extraction time or temperature as well as the molar ratio of 1 to aromatic heterocyclic sulfur compound was also studied.
Keywords:1  2-Dimethylimidazolium IL  Adsorbent  Desulfurization  Recyclability
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