Plasmonic rhenium trioxide self-assembled microtubes for highly sensitive,stable and reproducible surface-enhanced raman spectroscopy detection |
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Institution: | 1. College of Sciences, China Jiliang University, Hangzhou 310018, China;2. Institute of Industrial and Consumer Product Safety, Chinese Academy of Inspection and Quarantine, Beijing 100176, China;3. Key Laboratory of Intelligent Manufacturing Quality Big Data Tracing and Analysis of Zhejiang Province, China Jiliang University, Hangzhou 310018, China |
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Abstract: | Compared with noble metals, improving the sensitivity of semiconducting surface-enhanced Raman scattering (SERS) substrates is of great significance to their fundamental research and practical application of Raman spectroscopy. Herein, a simple chemical method is developed to synthesize a rhenium trioxide (ReO3) microtubes assembled with highly crystalline nanoparticles. The ReO3 microtubes show a strong and well-defined surface plasmon resonance (SPR) behavior in visible region, which is rare for non-noble metals. As a low-cost SERS substrate, the plasmonic ReO3 microtubes exhibit a Raman enhancement factor of 8.9 × 105 and a lowest detection limit of 1.0 × 10?9 mol/L for phenolic pollutants. Moreover, these ReO3 microtubule SERS substrates show excellent chemical stability and can resist the corrosion of strong acids and bases. |
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