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| The facile insertion of β-keto sulfones to arynes： The direct preparation of polysubstituted ortho-keto benzyl sulfones | |
| 作者姓名： | Jian Xue ;Lu Ling Wu ;Xian Huang |
| 作者单位： | a Department of Chemistry, Zhejiang University Campus Xixi, Hangzhou 310028, PR China;b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China |
| 基金项目： | We are grateful to the National Natural Science Foundation of China (Nos. 20332060 and 2472072). |
| 摘 要： | One novel carbon-carbon bond insertion reaction of arynes has been developed. By this reaction β-keto sulfones can insert the triple bond of arynes to prepare polysubstituted ortho-keto benzyl sulfones. |
| 关 键 词： | 内反应 C-C键 β-酮 砜 芳炔 |
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