| Acyldesilylation of 5-Trimethylsilyl-2-furancarboxaldehyde |
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| 作者姓名： | Hu Ri PIAO Zhe Shan QUAN Kouji NAKAYAMA Akira TANAKA |
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| 作者单位： | a School of Pharmacy, Yanbian University, Yanji, 133000;b Faculty of Pharmaceutical Sciences, Josai University, Saitama, Japan 35002 |
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| 摘 要： | 5－Acyl－2－furancarboxaldehydes2arelmpol－tantIntermedlateslforsynthesizingnaturallyoccuTTingfuranoldfattyacidswhichhaveantloxldanteffectsandantlneoplastlcactlvltlesInbiologicalsystems－．Nakayamaela尸reportedsuccessfulhalodesllylatlonofethyls－trlm...
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| 关 键 词： | 2-Acyl-5-dlchloromethylmra 5-Acyl-2-furancarboxaldehyde 5-Trlmethylsilyl-2-furancarboxaldehyde，Acyldesilylation |
Acyldesilylation of 5-Trimethylsilyl-2-furancarboxaldehyde |
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| Hu Ri PIAO, Zhe Shan QUAN, Kouji NAKAYAMA, Akira TANAKA.Acyldesilylation of 5-Trimethylsilyl-2-furancarboxaldehyde[J].Chinese Chemical Letters,1999,10(1):11-12. |
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| Authors: | Hu Ri PIAO Zhe Shan QUAN Kouji NAKAYAMA Akira TANAKA |
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| Institution: | a School of Pharmacy, Yanbian University, Yanji, 133000;b Faculty of Pharmaceutical Sciences, Josai University, Saitama, Japan 35002 |
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| Abstract: | Acyldesilylation of 5-trimethylsilyl-2-furancarboxaldehyde with acyl chlorides was investigated and the unexpected 5-acyl-2-dichloromethylfuran were obtained as main products. The expected 5-acyl-2-furancarboxaldehydes were also found after hydrolyzing of the corresponding dichloro-compounds. |
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| Keywords: | 2-Acyl-5-dlchloromethylmra 5-Acyl-2-furancarboxaldehyde 5-Trlmethylsilyl-2-furancarboxaldehyde Acyldesilylation |
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