Chiral Synthesis of 13-Acetyl-12-hydroxy-podocarpane-8, 11,13-triene-7-one |
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| Authors: | An Pai LI Yong Hong GAN Xiao Shui PENG Tong Xing WU Xin Fu PAN |
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| Institution: | An Pai LI,Yong Hong GAN,Xiao Shui PENG,Tong Xing WU,Xin Fu PAN* Department of Chemistry,National Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000 |
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| Abstract: | An enantioselective synthetic route to (+)-13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one 1a and (-)-13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one 1b was developed from (S)-(-)-(-cyclocitral 8a and (R)-(+)-(-cyclocitral 8b. |
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| Keywords: | Synthesis enantioselective podocarpane anisic chiral |
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