| One-pot Synthesis of Divalent and Trivalent Cluster Mannosides via Ugi Four-component Reaction |
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| 作者姓名： | XiaoRuZHANG YingXiaLI ShiDongCHU KunYuYU HuaShiGUAN |
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| 作者单位： | InstituteofMarineDrugs,OceanUniversityofChina,Qingdao266003 |
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| 摘 要： | The Ugi four-component reaction (U-4CR) was utilized to prepare divalent and trivalent cluster mannosides. Thus, two target compounds 6 and 8 were obtained efficiently using carboxymethyl 2, 3, 4, 6-tetra-O-acety-α-D-mannopyranoside 4 as acid component, and 1, 6-hexanediamine or tris(2-aminoethyl)amine as the multivalent scaffolds.
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| 关 键 词： | 一埚法 合成 二价甘露糖苷 三价甘露糖苷 Ugi反应 四组分反应 碳水化合物 |
One-pot Synthesis of Divalent and Trivalent Cluster Mannosides via Ugi Four-component Reaction |
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| XiaoRuZHANG YingXiaLI ShiDongCHU KunYuYU HuaShiGUAN.One-pot Synthesis of Divalent and Trivalent Cluster Mannosides via Ugi Four-component Reaction[J].Chinese Chemical Letters,2003,14(11):1130-1132. |
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| Authors: | Xiao Ru ZHANG Ying Xia LI Shi Dong CHU Kun Yu YU Hua Shi GUAN |
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| Abstract: | The Ugi four-component reaction (U-4CR) was utilized to prepare divalent and trivalent cluster mannosides. Thus, two target compounds 6 and 8 were obtained efficiently using carboxymethyl 2, 3, 4, 6-tetra-O-acetyl--D-mannopyranoside 4 as acid component, and 1, 6-hexanediamine or tris(2-aminoethyl)amine as the multivalent scaffolds. |
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| Keywords: | Ugi reactions cluster mannosides glycocluster |
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