| The Optical Resolution of Chiral Tetrahedrone-type Clusters Contai- ning SCoFeM (M=Mo or W) Using High Performance Liquid Chromatography Chiral Stationary Phase |
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| 作者姓名： | Xiao Qian HAN Yong Min LI Yu Hua ZHANG Sheng Xiang JIANG Li Ren CHEN* Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou |
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| 作者单位： | Xiao Qian HAN，Yong Min LI，Yu Hua ZHANG，Sheng Xiang JIANG，Li Ren CHEN* Lanzhou Institute of Chemical Physics，Chinese Academy of Sciences，Lanzhou 730000 |
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| 摘 要： | Optical resolution using high performance liquid chromatography chiral stationary phases has been widely used in many modern research fields such as asymmetric synthesis, asymmetric catalytic and separation of racemic pharmaceuticals. In the past years, various chiral stationary phases have been developed and have been commercially available1. Among them, polysaccharide based phases are the widely used CSPs. A wide variety of enantiomeric compounds including chiral aromatic alcohols, enant…
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The Optical Resolution of Chiral Tetrahedrone-type Clusters Contai- ning SCoFeM (M=Mo or W) Using High Performance Liquid Chromatography Chiral Stationary Phase |
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| Xiao Qian HAN,Yong Min LI,Yu Hua ZHANG,Sheng Xiang JIANG,Li Ren CHEN* Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou .The Optical Resolution of Chiral Tetrahedrone-type Clusters Contai- ning SCoFeM (M=Mo or W) Using High Performance Liquid Chromatography Chiral Stationary Phase[J].Chinese Chemical Letters,2002,13(12). |
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| Authors: | Xiao Qian HAN Yong Min LI Yu Hua ZHANG Sheng Xiang JIANG Li Ren CHEN |
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| Abstract: | Amylose tris (phenylcarbamate) chiral stationary phase (ATPC-CSP) was prepared and used for optical resolution of clusters 1 and 2. n-Hexane/2-propanol ( 99/1; v/v) were found to be the most suitable mobile phase on ATPC-CSP. |
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| Keywords: | Optical resolution amylose tris (phenylcarbamate) chiral stationary phase chiral tetrahedrone type cluster |
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