| A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes |
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| 作者姓名： | Mengyang Bai Guanyu Tao Zhenxing Liu Lili Wang Zheng Duan |
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| 作者单位： | College of Chemistry, Green Catalysis Center, International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University |
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| 基金项目： | financial support from the National Natural Science Foundation of China (Nos. 21672193, 21272218)；;the Key Scientific and Technological Project of Henan Province (No. 202102310327)；;the Postdoctoral Research Grant in Henan Province (No. 001803004)；;the Programme of Introducing Talents of Discipline to Universities (111 Project, No. D20003)； |
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| 摘 要： | A facile access to mono-C-alkynyl-o-carboranes from o-carboranes and arylsulfonylacetylenes was developed. This facile process tolerates a wide variety of functional groups, occurs at mild conditions in onepot procedure with short reaction time. The obtained mono-C-alkynyl-o-carboranes can be easily derivatized to synthesize 1,2-difunctionalized o-carboranes. This work provides a useful tool for the functionalization of o-carboranes.
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| 收稿时间： | 21 March 2021 |
A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes |
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| Mengyang Bai,Guanyu Tao,Zhenxing Liu,Lili Wang,Zheng Duan.A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes[J].Chinese Chemical Letters,2022,33(1):201-204. |
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| Abstract: | A facile access to mono-C-alkynyl-o-carboranes from o-carboranes and arylsulfonylacetylenes was developed. This facile process tolerates a wide variety of functional groups, occurs at mild conditions in one-pot procedure with short reaction time. The obtained mono-C-alkynyl-o-carboranes can be easily derivatized to synthesize 1,2-difunctionalized o-carboranes. This work provides a useful tool for the functionalization of o-carboranes. |
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