| Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene |
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| 作者姓名： | Yuan Yuan WANG Hui SUN Juan LI Dong JIANG Li Yi DAI |
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| 作者单位： | Center for the Chemistry of Ionic Liquids, East China Normal University （E.C.N.U）, Shanghai 200062 |
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| 基金项目： | Acknowledgments This work was financially supported by the Ministry of Education of China （No. 105075） |
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| 摘 要： | Room temperature ionic liquids (RTILs) as advanced, technological solvents can be designed to fit a particular application. They used as green “media and/or catalysts” for chemical synthesis have been extensively reviewed recently. RTILs1 not only show …
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| 关 键 词： | Et3NHCl-AlCl3离子液体 引发剂 1 3-戊二烯 苯乙烯 阳离子共聚合作用 |
| 收稿时间： | 2005-04-04 |
Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene |
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| Yuan Yuan WANG Hui SUN Juan LI Dong JIANG Li Yi DAI.Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene[J].Chinese Chemical Letters,2006,17(1):117-120. |
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| Authors: | Yuan Yuan WANG Hui SUN Juan LI Dong JIANG Li Yi DAI |
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| Abstract: | The random copolymer poly (1, 3-pentadiene-co-styrene) formed through cationic copolymerization using the triethylamine hydrochloride and hydrous aluminium chloride (Et3NHCl-AlCl3) room temperature ionic liquid as initiating agent in toluene was analyzed using IR spectra in conjunction with gel permeation chromatography (GPC). The room temperature ionic liquid was found to have high initiatic activity for copolymerization. |
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| Keywords: | Et3NHCl-AlCl3 ionic liquid 1 3-pentadiene styrene cationic copolymerization |
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