Tailorable carbazolyl cyanobenzene-based photocatalysts for visible light-induced reduction of aryl halides |
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Institution: | 1. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China;2. School of Pharmacy, Nantong University, Nantong 226001, China |
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Abstract: | Herein, a series of carbazolyl cyanobenzene (CCB)-based organic photocatalysts with a broad range of photoredox capabilities were designed and synthesized, allowing precise control of the photocatalytic reactivity for the controllable reduction of aryl halides via a metal-free process. The screened-out CCB (5CzBN), a metal-free, low-cost, scalable and sustainable photocatalyst with both strong oxidative and reductive ability, exhibits superior performance for both dehalogenation and CC bond-forming arylation reactions. |
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Keywords: | Organic photocatalyst Halide Photocatalyst Reduction |
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