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A novel Mo-based oxide β-SnMoO_4 as anode for lithium ion battery
作者姓名:Huiwen Zheng  Hailin Zhang  Yu Fan  Ge Ju  Hongbin Zhao  Jianhui Fang  Jiujun Zhang  Jiaqiang Xu
作者单位:NEST Lab, Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China; ; College of Sciences & Institute for Sustainable Energy, Shanghai University, Shanghai 200444, China; ; Shanghai CENAT New Energy Co., Ltd., Shanghai 201815, China
基金项目:The authors acknowledge the support of National Key Research; Development Program of China (No. 2017YFB0102900); National Key Research and Development Plan (No. 2017YFB0102200); the Shanghai Committee of Science and Technology, China (No. 17010500500) and the Shanghai Municipal Education Commission (Peak Discipline Construction program).
摘    要:Recently,the development of new electrode materials for lithium-ion batteries(LIBs)has received intensive attention.As an important family of inorganic materials,mixed Mo-based transition metal oxides system is focused as anode materials.In the present work,a simple route has been adopted for the synthesis of layered-flake-likeβ-SnMo04 Nano-assemblies,which have been explored as potential anode materials for the first time in lithium-ion battery(LIB).Overall,the current reports on metal molybdate as anode materials are still rarely.As the anode material for LIBs,it was observed that the fabricated anode is capable of delivering a steady state capacity of almost 400 mAh/g up to 300 cycles under the influence of200 mA/g current density.Further,the anode material is suitable for use as a rated capacity anode because of its high current density tolerance.The present study can be further extended for the generation of a wide variety of other novel materials for multidisciplinary energy related applications.

关 键 词:β-SnMoO4  nanomaterials  Nanoflake  structure  Lithium  storage  performance  Novel  anode  material  LIBS
收稿时间:25 January 2019

A novel Mo-based oxide β-SnMoO4 as anode for lithium ion battery
Huiwen Zheng,Hailin Zhang,Yu Fan,Ge Ju,Hongbin Zhao,Jianhui Fang,Jiujun Zhang,Jiaqiang Xu.A novel Mo-based oxide β-SnMoO4 as anode for lithium ion battery[J].Chinese Chemical Letters,2020,31(1):210-216.
Authors:Huiwen Zheng  Hailin Zhang  Yu Fan  Ge Ju  Hongbin Zhao  Jianhui Fang  Jiujun Zhang  Jiaqiang Xu
Institution:NEST Lab, Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China; College of Sciences & Institute for Sustainable Energy, Shanghai University, Shanghai 200444, China; Shanghai CENAT New Energy Co., Ltd., Shanghai 201815, China
Abstract:Recently, the development of new electrode materials for lithium-ion batteries (LIBs) has received intensive attention. As an important family of inorganic materials, mixed Mo-based transition metal oxides system is focused as anode materials. In the present work, a simple route has been adopted for the synthesis of layered-flake-like β-SnMoO4 Nano-assemblies, which have been explored as potential anode materials for the first time in lithium-ion battery (LIB). Overall, the current reports on metal molybdate as anode materials are still rarely. As the anode material for LIBs, it was observed that the fabricated anode is capable of delivering a steady state capacity of almost 400 mAh/g up to 300 cycles under the influence of 200 mA/g current density. Further, the anode material is suitable for use as a rated capacity anode because of its high current density tolerance. The present study can be further extended for the generation of a wide variety of other novel materials for multidisciplinary energy related applications.
Keywords:β-SnMoO4 nanomaterials  Nanoflake structure  Lithium storage performance  Novel anode material  LIBs  
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