|
|||||
|
|
Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer |
|
| Authors: | Feng-Hua Zhao Ruo-Jin Liu Xiao-Yan Yu Kimiyoshi-Naito Cheng-Chun Tang Xiong-Wei Qua Qing-Xin Zhang |
| Institution: | a Institute of Polymer Science and Engineering, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China; b Key Lab for Micro-and Nano-Scale Boron Nitride Materials in Hebei Province, Hebei University of Technology, Tianjin 300130, China; c National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba-city, Ibaraki 305-0047, Japan |
| Abstract: | A novel naphthyl-based self-catalyzed phthalonitrile monomer was prepared via nucleophilic displacement reaction. The structure was characterized by Fourier infrared spectrum (FT-IR) and nuclear magnetic resonance (1H NMR). The polymerization mechanism was explored. Thermal properties were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), which demonstrated self-promoted behavior and excellent heat resistance. |
| Keywords: | Phthalonitrile polymer Self-catalyzed Thermal properties Heat resistance |
| 本文献已被 CNKI 等数据库收录！ | |
| 点击此处可从《中国化学快报》浏览原始摘要信息 | |
| 点击此处可从《中国化学快报》下载免费的PDF全文 | |