| Reduction of Sulphur-containing Aromatic Nitro Compounds with Hydrazine Hydrate over Iron(III) Oxide-MgO Catalyst |
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| 作者姓名： | Qi Xun SHI Rong Wen LU Zhu Xia ZHANG De Feng ZHAO State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian |
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| 作者单位： | Qi Xun SHI，Rong Wen LU，Zhu Xia ZHANG，De Feng ZHAO State Key Laboratory of Fine Chemicals，Dalian University of Technology，Dalian 116012 |
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| 摘 要： | Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron(III) oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst.
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Reduction of Sulphur-containing Aromatic Nitro Compounds with Hydrazine Hydrate over Iron(III) Oxide-MgO Catalyst |
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| Qi Xun SHI,Rong Wen LU,Zhu Xia ZHANG,De Feng ZHAO State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian .Reduction of Sulphur-containing Aromatic Nitro Compounds with Hydrazine Hydrate over Iron(III) Oxide-MgO Catalyst[J].Chinese Chemical Letters,2006(4). |
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| Authors: | Qi Xun SHI Rong Wen LU Zhu Xia ZHANG De Feng ZHAO State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian |
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| Institution: | Qi Xun SHI,Rong Wen LU,Zhu Xia ZHANG,De Feng ZHAO State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012 |
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| Abstract: | Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron(III) oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst. |
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| Keywords: | Iron(III) oxide-MgO catalyst hydrazine hydrate sulphur-containing aromatic nitro compounds reduction |
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