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Recent progress on pure organic room temperature phosphorescence materials based on host-guest interactions
Authors:Guojuan Qu  Yaopeng Zhang  Xiang Ma
Institution:1. Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai 200237, China;2. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
Abstract:Pure organic room temperature phosphorescence (RTP) has been attracting a lot interest recently. So far, many strategies have succeeded in achieving efficient organic RTP materials by increasing the rate of intersystem crossing (ISC) and suppressing non-radiative transitions. In supramolecular chemistry, the control and regulation of molecular recognition based on the role of the host and guest in supramolecular polymers matrix, has attracted much attention. Recently, researchers have successfully achieved room temperature phosphorescence of pure organic complexes through host-guest interactions. The host molecule specifically includes the phosphorescent guest to reduce non-radiative transitions and enhance room temperature phosphorescence emission. This review aims to describe the developments and achievements of pure organic room temperature phosphorescence systems through the mechanism of host-guest interactions in recent years, and demonstrates the exploration and pursuit of phosphorescent materials of researchers in different fields.
Keywords:Corresponding author    Pure organic room temperature phosphorescence  Host-guest interactions  Supramolecule  Macrocyclic structure  Film matrix  Crystal matrix
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