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Preparation of safe water–lipid mixed electrolytes for application in ion capacitor
摘    要:Aqueous electrolytes are safe, economic, and environmentally friendly. However, they have a narrow potential window. On the other hand, organic electrolytes exhibit good thermodynamic stability but are inflammable and moisture sensitive. In this study, we prepared water–PEG–lipid ternary electrolytes(TEs). To combine the advantages of water, polyethylene glycol(PEG) and propylene carbonate(PC). The nonflammable mixed electrolytes exhibited a wide potential window of about 2.8 V due to the beneficial effects of PEG and PC. Using these TEs, a lithium manganate–active carbon ion capacitor could be operated at 2.4 V with an energy density of 32 Wh/kg, based on the total active electrode material(current density of 3.3 m A/cm~2). This value was significantly higher than that achieved using an aqueous electrolyte, thereby rationalizing the higher energy density.

收稿时间:1 April 2020

Preparation of safe water–lipid mixed electrolytes for application in ion capacitor
Authors:Miaofeng Huang  Aihua Tang  Zhenyin Wang  Jingkun Shi  Xiaoping Jiang  Chubin Wan  Xin Ju
Institution:1. University of Science and Technology Beijing, Beijing 100083, China;2. Qilu University of Technology (Shandong Academy of Sciences), Ji’nan 250014, China
Abstract:Aqueous electrolytes are safe, economic, and environmentally friendly. However, they have a narrow potential window. On the other hand, organic electrolytes exhibit good thermodynamic stability but are inflammable and moisture sensitive. In this study, we prepared water–PEG–lipid ternary electrolytes (TEs). To combine the advantages of water, polyethylene glycol (PEG) and propylene carbonate (PC). The nonflammable mixed electrolytes exhibited a wide potential window of about 2.8 V due to the beneficial effects of PEG and PC. Using these TEs, a lithium manganate–active carbon ion capacitor could be operated at 2.4 V with an energy density of 32 Wh/kg, based on the total active electrode material (current density of 3.3 mA/cm2). This value was significantly higher than that achieved using an aqueous electrolyte, thereby rationalizing the higher energy density.
Keywords:Safe electrolytes  Wide potential window  Ion capacitor  Moisture tolerant  Ternary electrolyte  Water–lipid mixed
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