| Photo-induced Coupling Reaction of 1, 1-Diphenyl-2, 2-dicyanoethylene with 10-Methyl-9, 10-dihydroacridine |
| |
| 作者姓名： | Thomas C.W.MAK |
| |
| 作者单位： | Department of |
| |
| 摘 要： | In a previous communication1, we reported a novel photo-induced coupling of 9-fluorenylidenemalononitrile 1 with the coenzyme NADH model 10-methyl-9, 10-dihydroacridine (AcrH2) to give 9-dicyanomethyl-9-(10-methyl-9-acridinyl)fluorene and proposed a mechanism involving photo-induced electron transfer-proton transfer and radical coupling. This is a scarce mechanism for the reaction of NADH models2, which usually takes place by a formal hydride transfer pathway3. In view of the novelty of t…
|
| 关 键 词： | 耦合反应 1，1-联苯-2，2-氰乙烯 10-甲基-9，10-二氢吖啶 结构分析 |
Photo-induced Coupling Reaction of 1, 1-Diphenyl-2, 2-dicyanoethylene with 10-Methyl-9, 10-dihydroacridine |
| |
| Thomas C.W.MAK.Photo-induced Coupling Reaction of 1, 1-Diphenyl-2, 2-dicyanoethylene with 10-Methyl-9, 10-dihydroacridine[J].Chinese Chemical Letters,2004,15(2):159-162. |
| |
| Authors: | Hong JIANG You Cheng LIU Guan Wu WANG Shi Wei LUO Quan Ming WANG Thomas C W MAK |
| |
| Institution: | Hong JIANG1,You Cheng LIU1,2 *,Guan Wu WANG1,Shi Wei LUO1,Quan Ming WANG3,Thomas C. W. MAK3* 1Department of Chemistry,University of Science and Technology of China,Hefei,Anhui 230026 2National Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000 3Department of Chemistry,The Chinese University of Hong Kong,Shatin,New Territories,Hong Kong SAR |
| |
| Abstract: | Diphenyl-2, 2-dicyanoethylene reacts with 10-methyl-9, 10-dihydroacridine in deaerated acetonitrile under irradiation with l>320 nm to give the coupling product 1, 1-diphenyl-1-(10-methyl-9-acridinyl)-2, 2-dicyanoethane, which has been characterized by X-ray crystallographic, MS and NMR analyses. |
| |
| Keywords: | Photo-induced coupling reaction 1 1-diphenyl-2 2-dicyanoethylene 10-methyl-9 10-dihydroacridine 1 1-diphenyl-1-(10-methyl-9-acridinyl)-2 2-dicyanoethane |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
