Facile preparation of antibacterial polymer coatings via thiol-yne click photopolymerization |
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Authors: | Chuan Zhou Yi-He Li Zhen-Hua Jiang Kwang-Duk Ahn Tian-Jiao Hu Qing-Hua Wang Chun-Hua Wang |
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Institution: | a Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073, China;
b Polymer Research Center, Korea Institute of Science and Technology, Seoul 136-791, Republic of Korea |
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Abstract: | Novel antibacterial polymer coatings were prepared by a facile thiol-yne click photopolymerization of 1-propargyl-3-alkyl-1,3-diazanyl-2,4-cyclopentadiene bromide (PAIM]Br) and tetra(3-mercapto-propionate) pentaerythritol (PETMP) (2:1 molar ratio) using 2,2-dimethoxy-2-phenylacetophenone (DMPA) as initiator. The antibacterial activity of the coatings was tested against Staphylococcus aureus (ATCC 292130) and Escherichia coli (ATCC 25922) by the dynamic shake method. The evaluation results revealed the antibacterial polymer coatings exhibited excellent inhibitory activity against S. aureus and E. coli, especially for S. aureus. |
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Keywords: | Antibacterial polymer Thiol-yne Click chemistry UV-curing Coatings |
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