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Facile preparation of antibacterial polymer coatings via thiol-yne click photopolymerization
Authors:Chuan Zhou  Yi-He Li  Zhen-Hua Jiang  Kwang-Duk Ahn  Tian-Jiao Hu  Qing-Hua Wang  Chun-Hua Wang
Institution:a Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073, China; b Polymer Research Center, Korea Institute of Science and Technology, Seoul 136-791, Republic of Korea
Abstract:Novel antibacterial polymer coatings were prepared by a facile thiol-yne click photopolymerization of 1-propargyl-3-alkyl-1,3-diazanyl-2,4-cyclopentadiene bromide (PAIM]Br) and tetra(3-mercapto-propionate) pentaerythritol (PETMP) (2:1 molar ratio) using 2,2-dimethoxy-2-phenylacetophenone (DMPA) as initiator. The antibacterial activity of the coatings was tested against Staphylococcus aureus (ATCC 292130) and Escherichia coli (ATCC 25922) by the dynamic shake method. The evaluation results revealed the antibacterial polymer coatings exhibited excellent inhibitory activity against S. aureus and E. coli, especially for S. aureus.
Keywords:Antibacterial polymer  Thiol-yne  Click chemistry  UV-curing  Coatings  
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