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Azopyridine-imidacloprid derivatives as photoresponsive neonicotinoids
Authors:Shen Li  Run-Jiang Song  Dong-Hui Wang  Xue Tian  Xu-Sheng Shao  Zhong Li
Institution:a Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China; b College of Life Science, Perking University, Beijing 100871, China
Abstract:A series of imidacloprid derivatives containing an azopyridine motif as a photoswitchable functional group were designed and synthesized. The new version of photoresponsive imidacloprid analogues showed improved solubility in comparison with their azobenzene analogues. 1.2 to 2-fold activity difference was observed for these azopyridine-imidacloprids against house fly (Musca domestica) and cowpea aphid (Aphis craccivora) upon irradiation.
Keywords:Azopyridine  Photoresponsive  Imidacloprid  Solubility  Insecticide  
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