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CO2和He在阳泉煤CH4饱和基质煤柱中的渗流特性
引用本文:汤放新,杨建丽,肖勇,刘振宇.CO2和He在阳泉煤CH4饱和基质煤柱中的渗流特性[J].燃料化学学报,2011,39(2):94-98.
作者姓名:汤放新  杨建丽  肖勇  刘振宇
作者单位:1.State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;; 2.Graduate University of Chinese Academy of Sciences, Beijing 100049, China;; 3.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;; 4.Shell International Exploration &Production B.V., Kesslerpark 1, 2288 GS Rijswijk, Netherlands
基金项目:荷兰壳牌国际勘探与发展公司合作项目,欧盟第六框架计划,煤转化国家重点实验室自主研究课题
摘    要:利用自行设计的自约束渗透装置,采用热导检测器在线跟踪穿透实验过程中CO2或He的渗透信号,在40℃条件下,对比研究了CO2和He在阳泉煤CH4饱和基质煤柱(φ6×13mm)中的渗透行为,讨论了煤对气体的吸附或吸取作用及孔隙气压对渗透率的影响.研究表明,有别于煤对He的作用,在CO2和CH4交替渗透时,不同的CH4吹扫时...

关 键 词:  CO2  CH4  渗透率  穿透实验
收稿时间:2010-04-11

Permeability of CO2 and He in Yangquan coal matrix-plug saturated by CH4
TANG Fang-xin,YANG Jian-li,XIAO Yong,LIU Zhen-yu,Niels van Wageningen.Permeability of CO2 and He in Yangquan coal matrix-plug saturated by CH4[J].Journal of Fuel Chemistry and Technology,2011,39(2):94-98.
Authors:TANG Fang-xin  YANG Jian-li  XIAO Yong  LIU Zhen-yu  Niels van Wageningen
Abstract:The CO2 permeability of Yangquan coal matrix-plug (φ 6×13mm) saturated by CH4 was studied by carrying out CO2 breakthrough tests at 40℃. The similar tests were performed with inert gas He for comparison. The breakthrough tests were performed in a self-confining flow cell equipped with an online thermal conductivity detector for continually monitoring the signal of CO2 or He. The imbibition of gas by coal and the influence of the pore gas pressure were investigated. It shows that unlike He there is significant residual CO2 left in the coal matrix even after CO2 was flushed by CH4 for 36h. It reveals that coal has stronger imbibition ability for CO2, which leads to the difference in its breakthrough time for different CH4 flushing time. No notable residual He is found during the breakthrough tests. He permeability is significantly higher than that of CO2. The obtained permeability coefficients of the coal plug with CO2 or He at the steady state are closely the same for the repeat tests. It implies that no significant structure change involved during the tests. The permeability coefficients varied with the pore gas pressure due to the existence of the influences of the pore wall, the swelling of coal and the adsorption boundary layer.
Keywords:CO2  CH4
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