| 工业Fe-Mn催化剂上费托合成反应动力学的研究 |
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| 引用本文： | 高琳,徐元源,李永旺.工业Fe-Mn催化剂上费托合成反应动力学的研究[J].燃料化学学报,2009,37(6):717-721. |
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| 作者姓名： | 高琳 徐元源 李永旺 |
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| 作者单位： | Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China |
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| 基金项目： | 国家杰出青年科学基金，国家自然科学基金重大项目 |
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| 摘 要： | 使用工业Fe-Mn催化剂，以搅拌釜反应器的实验数据为依据，受计算量子化学研究结果的启发，考察了两类费托合成反应机理，建立了相应的反应动力学模型并与文献模型进行了比较。结果表明，CO在氢参与下经含氧中间体解离的机理给出了最优的动力学模型，其与文献的结论一致。
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| 关 键 词： | 费托合成 反应动力学 CO氢助解离 |
| 收稿时间： | 2009-03-09 |
| 修稿时间： | 2009-07-19 |
Study on lumped kinetics model for Fischer-Tropsch synthesis over an industrial Fe-Mn catalyst |
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| GAO Lin,XU Yuan-yuan,LI Yong-wang.Study on lumped kinetics model for Fischer-Tropsch synthesis over an industrial Fe-Mn catalyst[J].Journal of Fuel Chemistry and Technology,2009,37(6):717-721. |
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| Authors: | GAO Lin XU Yuan-yuan LI Yong-wang |
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| Abstract: | A set of lumped kinetics models were developed from two kinds of F-T reaction mechanisms inspired on the basis of study on quantum chemistry in reference. The experimental data were measured in a continuous stirred tank reactor with an industrial Fe-Mn catalyst. It is concluded that the optimized model in analogy with the one in reference was derived from the mechanism of hydrogen assisted dissociation of CO through its oxygenate intermediate. |
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| Keywords: | Fischer-Tropsch lumped kinetics hydrogen assisted dissociation) |
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