| 丙烷在磷改性的HZSM—5上的芳构化反应 |
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| 引用本文： | 王心葵,解红娟.丙烷在磷改性的HZSM—5上的芳构化反应[J].燃料化学学报,1991,19(4):298-303. |
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| 作者姓名： | 王心葵 解红娟 |
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| 作者单位： | 中国科学院山西煤炭化学研究所 太原
(王心葵，解红娟，程爱华)，中国科学院山西煤炭化学研究所 太原(彭少逸) |
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| 摘 要： |
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| 关 键 词： | 丙烷 芳构化 磷 改性 分子筛 |
PROPANE AROMATIZATION OVER PHOSPHORUS MODIFIED HZSM-5 |
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| Wang Xinkui Xie Hongjuan Cheng Aihua Peng Shaoyi.PROPANE AROMATIZATION OVER PHOSPHORUS MODIFIED HZSM-5[J].Journal of Fuel Chemistry and Technology,1991,19(4):298-303. |
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| Authors: | Wang Xinkui Xie Hongjuan Cheng Aihua Peng Shaoyi |
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| Abstract: | The modification of HZSM-5 with phosphorus and it's effect on the propane aromatization were investigated by means of thermal balance,IR and probe reaction.A series of HZSM-5 catalysts doped with different amount of phosphorus were prepared.The results obtained showed that the addition of phosphorus with adequate amount to HZSM-5 can effectively suppress the cracking reaction and obviously enhance the selectivity of aimed products.Coke resistance and catalyst life are also improved.The reasons accounting for the wariations can be ascribed to the acidity changes due to the modification,that is,cracking sites with strongest acidity tend to convert in to aromatization ones which possess weaker acidity,mean while the number of these sites is also increased. |
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| Keywords: | HZSM-5 propane aromatization Brosted sites phosphoric acid |
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