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亚临界水条件下煤中汞的脱除
引用本文:王宝凤,王刚,李文,陈皓侃,李保庆.亚临界水条件下煤中汞的脱除[J].燃料化学学报,2004,32(5):513-516.
作者姓名:王宝凤  王刚  李文  陈皓侃  李保庆
作者单位:1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyaun 030001, China; 2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
基金项目:国家自然科学基金(90210001)。~~
摘    要:运用半连续反应装置对山西吴家坪煤中汞在亚临界水中的脱除规律进行了研究。考察了反应温度为290 ℃、320 ℃ 、350 ℃、 380 ℃,反应压力为5 MPa、10 MPa、15 MPa,萃取时间为10 min、30 min、60 min、100 min时对汞脱除率的影响。结果表明,在290 ℃~380 ℃,随着温度升高,汞脱除率明显增加;在5 MPa~15 MPa,压力越大,汞的脱除率也越大;在10 min~100 min,随着萃取时间的延长,汞脱除率增加;在380 ℃, 15 MPa, 1 h,汞的脱除率最大可达96%以上。

关 键 词:亚临界水      脱除  
文章编号:0253-2409(2004)05-0513-04
收稿时间:2004-05-08
修稿时间:2004年5月8日

Removal of mercury from coal by sub-critical water extraction
WANG Bao-feng.Removal of mercury from coal by sub-critical water extraction[J].Journal of Fuel Chemistry and Technology,2004,32(5):513-516.
Authors:WANG Bao-feng
Institution:WANG Bao-feng~
Abstract:The removal of mercury from coal using sub-critical water extraction in a semi-continuous reactor was studied. The effect of temperature, pressure and extraction time on the removal rate of mercury was examined. The results show that in the temperature range 290 ℃~380 ℃, the higher the temperature is, the larger the mercury removal rate is. And the mercury removal rate increases with reaction pressure and residence time under the pressures from 5 MPa to 15 MPa and residence time from 10 min to 100 min. The maximum removal rate of mercury can reach above 96% under the conditions of 380 ℃, 15 MPa and 60 min.
Keywords:sub-critical water  coal  mercury  removal
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