| 铁系无铬(NBC-1)型高温变换催化剂 Ⅳ.吸附性能及CO变换反应机理的研究 |
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| 引用本文： | 牟占军,高筠,刘全生,刁丽彤,金恒芳.铁系无铬(NBC-1)型高温变换催化剂 Ⅳ.吸附性能及CO变换反应机理的研究[J].燃料化学学报,1999(3). |
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| 作者姓名： | 牟占军 高筠 刘全生 刁丽彤 金恒芳 |
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| 作者单位： | 内蒙古工业大学化学工程系 |
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| 摘 要： | 通过程序升温脱附（ＴＰＤ）、程序升温表面反应（ＴＰＳＲ）及脉冲反应（ＰＳＲ）等化学物理技术，综合分析研究了铁系无铬（ＮＢＣ－１）型ＣＯ高温变换催化剂的吸附性能及化学反应特性。研究表明，ＮＢＣ－１型催化剂对Ｈ２Ｏ具有很强的吸附能力，不易吸附ＣＯ及ＣＯ２，该催化剂上水煤气变换反应的机理为氧化－还原（ｒｅｄｏｘ）反应机理
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| 关 键 词： | 水煤气变换催化剂，铁系无铬催化剂，化学吸附，变换反应机理 |
NON-CHROMIUM IRON-BASED (NBC-1) COHIGH TEMPERATURE SHIFT CATALYST ADSORPTION PERFORMANCE AND WATER-GAS SHIFT REACTION MECHANISM |
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| Mu ZhanjunGao YunLiu QuanshengDiao LitongJin Hengfang.NON-CHROMIUM IRON-BASED (NBC-1) COHIGH TEMPERATURE SHIFT CATALYST ADSORPTION PERFORMANCE AND WATER-GAS SHIFT REACTION MECHANISM[J].Journal of Fuel Chemistry and Technology,1999(3). |
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| Authors: | Mu ZhanjunGao YunLiu QuanshengDiao LitongJin Hengfang |
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| Institution: | Department fo Chemical EngineeringInner Mongolia Polytechnic UniversityHuhhot |
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| Abstract: | By using of some chemical physics technology, such as temperature programmed desorption (TPD), temperature programmed surface reaction (TPSR) and pulsed surface reaction (PSR), this thesis makes a thorough investigation on the adsorption performance and chemical reaction characteristics of the non-chromium iron-based (NBC-1) for CO high temperature shift reaction The results show that the NBC-1 catalyst surface has strong adsorption ability to H2O, weaker adsorption to CO and CO2, and that the Water Gas Shift reaction mechanism on this catalyst is the redoxreaction |
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| Keywords: | water-gas shift catalyst non-chromium iron-based catalyst chemical adsorption shift reaction mechanism |
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