| 微波条件下ZnCl2改性离子交换树脂催化改质生物油的研究 |
| |
| 引用本文： | 张凤,蒋晓原,楼辉,郑小明.微波条件下ZnCl2改性离子交换树脂催化改质生物油的研究[J].燃料化学学报,2011,39(12):901-906. |
| |
| 作者姓名： | 张凤 蒋晓原 楼辉 郑小明 |
| |
| 作者单位： | Institute of Catalysis, Department of Chemistry, Zhejiang University, Hangzhou 310028, China |
| |
| 基金项目： | 国家重点基础研究发展规划(973计划,2007CB210204) |
| |
| 摘 要： | 在微波加热条件下,以732型阳离子交换树脂和ZnCl2改性离子交换树脂为催化剂,添加乙醇为溶剂,对生物油进行催化酯化改质.比较研究了两种催化剂随催化剂用量、反应时间及反应温度改变对生物油改质效果的影响,同时考察了微波加热与传统水浴加热条件下催化剂的活性.结果表明,酯化过程中ZnC12改性离子交换树脂比732型树脂活性有...
|
| 关 键 词： | 微波 生物油 催化酯化 离子交换树脂 氯化锌 |
| 收稿时间： | 2011-01-19 |
Catalytic upgrading of bio-oil by ZnCl_2 exchanged resin with microwave |
| |
| ZHANG Feng,JIANG Xiao-yuan,LOU Hui,ZHENG Xiao-ming.Catalytic upgrading of bio-oil by ZnCl_2 exchanged resin with microwave[J].Journal of Fuel Chemistry and Technology,2011,39(12):901-906. |
| |
| Authors: | ZHANG Feng JIANG Xiao-yuan LOU Hui ZHENG Xiao-ming |
| |
| Institution: | ZHANG Feng,JIANG Xiao-yuan,LOU Hui,ZHENG Xiao-ming (Institute of Catalysis,Department of Chemistry,Zhejiang University,Hangzhou 310028,China) |
| |
| Abstract: | Esterification with microwave,as a new method to upgrade crude bio-oil,was brought forward according to the composition characteristics of bio-oil.Crude bio-oil was upgraded in ethanol using the 732# cation exchange resin and ZnCl2 exchanged resin as catalysts and using the microwave as heating resource.The results show that the ZnCl2 exchanged resin performs a higher activity duing the upgrading process and the heating by microwave can effectively promote the upgrading process compared to traditional water... |
| |
| Keywords: | microwave bio-oil catalytic esterfication cation exchange resin zinc chloride |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《燃料化学学报》浏览原始摘要信息 |
| 点击此处可从《燃料化学学报》下载免费的PDF全文 |
|
