| 晋城15号无烟煤的温和氧化 |
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| 引用本文： | 王玉高,魏贤勇,闫洪雷,刘静,柳方景,李鹏,宗志敏.晋城15号无烟煤的温和氧化[J].燃料化学学报,2013,41(7):819-825. |
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| 作者姓名： | 王玉高 魏贤勇 闫洪雷 刘静 柳方景 李鹏 宗志敏 |
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| 作者单位： | Key Laboratory of Coal Processing and Efficient Utilization (Ministry of Education), China University of Mining & Technology, Xuzhou 221116, China |
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| 基金项目： | National Basic Research Program of China(973 program,2011CB201302);National Natural Science Foundation of China(20936007,50974121,51074153 and 21276268);the Fund from National Natural Science Foundation of China for Innovative Research Group(51221462);Strategic Chinese-Japanese Joint Research Program(2013DFG60060);a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions |
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| 摘 要： | 用钌离子催化氧化法探究了晋城15号无烟煤(J15A)的结构特征,结果表明,J15A富含紧密的芳香性结构.在温和条件下,先用H2O2对J15A进行预处理,然后用NaOCl对其氧化从而生成苯多酸.结果表明,H2O2预处理可提高NaOCl氧化J15A生成苯多酸的产率,而且该方法可以高收率、高选择性地获取苯多酸化学品.
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| 关 键 词： | 无烟煤 苯多酸 温和氧化 |
| 收稿时间： | 2013-05-16 |
Mild oxidation of Jincheng No.15 anthracite |
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| WANG Yu-gao,WEI Xian-yong,YAN Hong-lei,LIU Jing,LIU Fang-jing,LI Peng,ZONG Zhi-min.Mild oxidation of Jincheng No.15 anthracite[J].Journal of Fuel Chemistry and Technology,2013,41(7):819-825. |
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| Authors: | WANG Yu-gao WEI Xian-yong YAN Hong-lei LIU Jing LIU Fang-jing LI Peng ZONG Zhi-min |
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| Institution: | (Key Laboratory of Coal Processing and Efficient Utilization(Ministry of Education),China University of Mining & Technology,Xuzhou 221116,China) |
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| Abstract: | Jincheng No.15 anthracite (J15A) was subjected to ruthenium ion-catalyzed oxidation to characterize its structural feature. The results show that J15A is abundant in peri-condensed aromatic structure. The NaOCl oxidation of J15A promoted by pretreatment with H2O2 was conducted under mild conditions to produce benzene polycarboxylic acids (BPCAs). The pretreatment with H2O2 is proved to enhance the yields of BPCAs. It is potential to obtain BPCAs in high yield and selectivity by NaOCl oxidation of pretreated J15A with H2O2. |
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| Keywords: | anthracite benzene polycarboxylic acid mild oxidation |
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