| 甲醇在HY分子筛上合成异构烃的研究 |
| |
| 引用本文： | 倪小明,谭猗生,韩怡卓.甲醇在HY分子筛上合成异构烃的研究[J].燃料化学学报,2006,34(5):637-639. |
| |
| 作者姓名： | 倪小明 谭猗生 韩怡卓 |
| |
| 作者单位： | 1. State Key Lab of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyaun 030001, China; 2 . Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
| |
| 摘 要： | 在以分子筛为催化剂的甲醇转化研究领域中，最为成功的是甲醇在ZSM-5分子筛上转化制汽油的研究。由于在孔道结构以及酸性质上，ZSM-5型分子筛有着不同于HM、HY等其他分子筛的特点，使得它在甲醇转化制汽油的反应中有着其他分子筛不可比拟的优势。
|
| 关 键 词： | 甲醇 HY分子筛 异构烃的选择性 |
| 文章编号： | 0253-2409（2006）05-0637-03 |
| 收稿时间： | 2005-12-06 |
| 修稿时间： | 2006-04-21 |
Study on the synthesis of isoalkanes by the reaction of methanol over HY catalyst |
| |
| NI Xiao-ming,TAN Yi-sheng,HAN Yi-zhuo.Study on the synthesis of isoalkanes by the reaction of methanol over HY catalyst[J].Journal of Fuel Chemistry and Technology,2006,34(5):637-639. |
| |
| Authors: | NI Xiao-ming TAN Yi-sheng HAN Yi-zhuo |
| |
| Institution: | 1. State Key Lab of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyaun 030001, China; 2 . Graduate School of the Chinese Academy of Sciences, Beifing 100039, China |
| |
| Abstract: | The methanol conversion over HY zeolite was studied at 1atm, 280℃~360℃. The effects of temperature, GHSV, and reaction time on the performance of reaction of methanol were discussed. The results showed that HY catalyst gave isoalkanes with high selectivity. Higher temperature(280℃~340℃) and lower GHSV decreased the selectivity to dimethyl ether and increased that to C2，C3，i-C4 ，i-C5. With the further increase of temperature, the selectivity of C2，C3 increased while that to i-C4 ，i-C5 decreased. The selectivity to isoalkanes decreased quickly with the reaction time. |
| |
| Keywords: | methanol conversion HY isoalkanes selectivity |
| 本文献已被 维普 万方数据 等数据库收录！ |
| 点击此处可从《燃料化学学报》浏览原始摘要信息 |
| 点击此处可从《燃料化学学报》下载免费的PDF全文 |
|
