Microwave-accelerated cross-metathesis reactions of N-allyl amino acid substrates |
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| Authors: | Sally-Ann Poulsen Laurent F Bornaghi |
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| Institution: | Eskitis Institute for Cell and Molecular Therapies, Griffith University, Nathan campus, Brisbane 4111, Australia |
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| Abstract: | Microwave heating has been utilised for the cross-metathesis reaction of N-allyl amino acid substrates to generate olefin homodimers. Remarkable acceleration of the cross-metathesis reaction (minutes compared to hours) over conventional reflux heating was observed. In addition, improved reaction yields and similar E/Z ratios for the cross-metathesis products were achieved. |
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| Keywords: | Olefin Cross-metathesis Microwave Amino acids N-Allylation |
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