Steric selectivity in oxidations of diols |
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Authors: | Michael P Doyle Robert L Dow Vahid Bagheri William J Patrie |
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Institution: | Department of Chemistry, Hope College, Holland, Michigan 49423 USA |
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Abstract: | Oxidations of 2,2-disubstituted-1,4-butanediols by the combination of nickel(II) bromide and benzoyl peroxide and by trityl tetrafluoroborate produce β,β-disubstituted-γ-butyrolactones with exceptional selectivity. |
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