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Steric selectivity in oxidations of diols
Authors:Michael P Doyle  Robert L Dow  Vahid Bagheri  William J Patrie
Institution:Department of Chemistry, Hope College, Holland, Michigan 49423 USA
Abstract:Oxidations of 2,2-disubstituted-1,4-butanediols by the combination of nickel(II) bromide and benzoyl peroxide and by trityl tetrafluoroborate produce β,β-disubstituted-γ-butyrolactones with exceptional selectivity.
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