Evidence for the involvement of a tetrahedral intermediate in H-D exchange of C-2 proton in thiazolium ion |
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Authors: | K Karimian I Ganjian M Askari |
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Institution: | Institute of Biochemistry and Biophysics, University of Tehran, P.O. Box 314-1700, Tehran, Iran. |
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Abstract: | Mechanism of H-D exchange of C-2 proton of thiazolium ion has been examined by PMR spectroscopy. Involvement of a tetrahedral intermediate, prerequisite to the exchage reaction, is proposed. |
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