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Evidence for the involvement of a tetrahedral intermediate in H-D exchange of C-2 proton in thiazolium ion
Authors:K Karimian  I Ganjian  M Askari
Institution:Institute of Biochemistry and Biophysics, University of Tehran, P.O. Box 314-1700, Tehran, Iran.
Abstract:Mechanism of H-D exchange of C-2 proton of thiazolium ion has been examined by PMR spectroscopy. Involvement of a tetrahedral intermediate, prerequisite to the exchage reaction, is proposed.
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