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Synthesis of new di-anchoring organic sensitizer based on quinoxaline acceptor for dye-sensitized solar cells
Authors:Jong Min Park  Chang Young Jung  Joong Hyun Cho  Dae Hyun Kim  Yue Wang  Jae Yun Jaung
Institution:Department of Organic and Nano Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 133-791, South Korea
Abstract:New quinoxaline-based organic sensitizer bearing di-anchoring group for dye-sensitized solar cells (DSSCs) was synthesized from diethyl 4,5-diaminophthaltate, in which was prepared under mild condition by using Takehito’s method. The synthesized sensitizer was compared with mono-anchoring sensitizer through absorption spectra, emission spectra, J-V curve, and IPCE spectra, indicating the di-anchoring group leads to a noticeable improvement of Jsc value owing to more efficient intramolecular charge transfer and channel number increment.
Keywords:Dye-sensitized solar cells  Anchoring group  Metal-free organic sensitizer  Quinoxaline  Phenothiazine
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