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Synthesis of the sedum and related alkaloids: A personal perspective |
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| Authors: | Roderick W Bates |
| Institution: | Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore |
| Abstract: | Significant recent contributions to the synthesis of the sedum alkaloids are discussed. Related compounds, such as pinidinol, porantheridine, dumetorine and the tetraponerines are also included. The syntheses are categorised according to the key motif or chemistry employed: isoxazolidines, metathesis, asymmetric aza-Michael, heterocycle lithiation, organocatalysis, aromatic heterocycles and chiral imines. |
| Keywords: | BIPHEPHOS CDI carbonyl diimidazole DIAD di-isopropylazodicarboxylate DEAD diethylazodicarboxylate DMA IBX 2-idoxybenzoic acid mcpba Me-CBS 2-methyl-CBS oxaborolidine Phth phthaloyl PMB PPTS PS-PPTS p-TsOH TMG tetramethyl guanidine Alkaloids Synthesis Sedum |
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