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Determination of absolute configuration of Pandanus alkaloid, pandamarilactonine-A, by first asymmetric total synthesis
Authors:Hiromitsu Takayama  Rie Sudo  Mariko Kitajima
Institution:Graduate School of Pharmaceutical Sciences, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
Abstract:The absolute configuration of pandamarilactonine-A, a pyrrolidine alkaloid, was established on the basis of total synthesis starting from l-prolinol. An insight into the mechanism of the low enantiomeric purity of natural pandamarilactonine-A is discussed.
Keywords:Pyrrolidine alkaloid  Asymmetric total synthesis  Absolute configuration  Optical purity
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