Palladium catalyzed cross-dimerization of terminal acetylenes and acrylates |
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| Authors: | Shanshan Chen Shi-Hang Xie Cheng-Ying Ai Xiu-Li Zhang |
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| Institution: | Division of Applied Chemistry, School of Natural Sciences, Anhui Agricultural University, Hefei 230036, China |
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| Abstract: | A palladium catalyzed oxidative cross-coupling reaction between terminal alkynes and acrylates was developed. In the presence of palladium catalyst and copper(II) acetate as oxidant, the cross dimerization products with were formed. This protocol provides a novel method to construct the tetrasubstituted functionalized alkenes. |
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| Keywords: | Palladium catalyst Alkynes Acrylates Cross-dimerization Conjugated skeleton |
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