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Molybdenum pentachloride (MoCl5) or molybdenum dichloride dioxide (MoO2Cl2): advanced catalysts for thioacetalization of heterocyclic, aromatic and aliphatic compounds
Authors:Shyamaprosad Goswami  Annada C Maity
Institution:Department of Chemistry, Bengal Engineering and Science University, Shibpur, Howrah 711 103, India
Abstract:A new, convenient and mild method for thioacetalization of heterocyclic, aromatic and aliphatic compounds catalyzed by MoCl5 or MoO2Cl2 is described. This novel method is important for the synthesis of the difficult to prepare heterocyclic thioacetals such as the pterin thioacetals and it offers significant advantages such as high conversion, short reaction times and simplicity in operation.
Keywords:Heterocyclic aldehydes  1  3-Propanedithiol  Thioacetalization  Heterocyclic thioacetals  Molybdenum pentachloride  Molybdenum dichloride dioxide
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