Ligand-assisted, copper-catalyzed enantioselective benzylic amination |
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| Authors: | Dipti N Barman |
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| Institution: | Department of Chemistry and Biochemistry, University of Oklahoma, Norman, OK 73019, USA |
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| Abstract: | Several classes of ligands, including α-amino acids, diamines, diphosphines, bis-oxazolines, and diimines, support efficient copper-catalyzed amination of benzylic hydrocarbons by anhydrous chloramine-T. Catalysts derived from homochiral ligands, particularly chiral diimines, effect aminosulfonation with low to moderate enantioselectivity. |
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| Keywords: | Hydrocarbon amination Ligand-assisted copper catalysis Enantioselective Chloramine-T |
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