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Copper- and phosphine-free Sonogashira coupling reactions of aryl iodides catalyzed by an N,N-bis(naphthylideneimino)diethylenetriamine-functionalized polystyrene resin supported Pd(II) complex under aerobic conditions
Authors:Mohammad Bakherad  Amir H Amin  Ali Keivanloo  Bahram Bahramian  Mersad Raeissi
Institution:School of Chemistry, Shahrood University of Technology, Shahrood, Iran
Abstract:A polymer-supported palladium(II) N,N-bis(naphthylideneimino)diethylenetriamine complex is found to be a highly active catalyst for Sonogashira coupling reactions. The reactions are performed under copper- and phosphine-free conditions in an air atmosphere. The palladium catalyst is easily separated, and can be reused several times without significant loss in catalytic activity.
Keywords:Copper- and phosphine-free  Sonogashira reaction  Supported catalyst  Aryl iodides
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