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Multidentate aminophenol ligands prepared with Mannich condensations
Authors:Christine S Higham  Janet L Shaw  Christopher J Ziegler
Institution:a Department of Chemistry, College of the Holy Cross, Worcester, MA 01610, USA
b Department of Chemistry, University of Akron, Akron, OH 44325, USA
Abstract:Mannich condensations were used to prepare a series of multidentate aminophenol compounds from ethylenediamine, various amounts of paraformaldehyde and 2,4-disubstituted phenols. One of these diaminotetraphenol compounds was reacted with Zn(OAc)2·2H2O and the resulting solid state structure of the pentacoordinated Zn(II) compound was determined by single crystal X-ray diffraction analysis.
Keywords:Mannich condensation  Zn(II)  Benzoxazine
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