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Catalytic enantioselective Mukaiyama aldol reaction via a chiral indium(III)-pybox complex |
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| Authors: | Fan Fu |
| Institution: | School of Physical and Mathematical Sciences, Division of Chemistry and Biological Chemistry, Nanyang Technological University, 1 Nanyang Walk, Blk 5, Level 3, Singapore 637616, Singapore |
| Abstract: | A chiral indium(III) complex prepared from indium triflate and a pybox ligand has been developed to give good yields and enantioselectivities (up to 92% ee) in the addition of (1-methoxy-2-methyl-propenyloxy)-trimethylsilane to various aromatic and aliphatic aldehydes via the Mukaiyama aldol reaction. |
| Keywords: | Catalytic Chiral indium complex Enantioselective Mukaiyama aldol |
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