Synthesis of a designed sesquiterpenoid that forms useful composites with peptides and related oligomers |
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Authors: | Kenneth V LawsonTristan E Rose Patrick G Harran |
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Institution: | Department of Chemistry and Biochemistry, University of California, 607 Charles E. Young Drive East, Los Angeles, CA 90095-1569, United States |
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Abstract: | Efficient desymmetrization of isophthalaldehyde allows a scalable asymmetric synthesis of cinnamylated sesquiterpenoid 1. We have shown that 1 forms useful, property-altered composites with peptides and related oligomers. The current synthesis promises to expand those efforts considerably. |
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