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A general and selective zinc-catalyzed oxidation of sulfides to sulfoxides
Authors:Xiao-Feng Wu
Institution:Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou 310018, Zhejiang Province, PR China
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany
Abstract:A general zinc-catalyzed oxidation of sulfides to sulfoxides has been developed. All the reactions proceeded at room temperature. Hydrogen peroxide was used as a green oxidant. Twenty-one examples of sulfoxides were prepared in moderate to excellent yields.
Keywords:Zinc catalyst  Sulfide  Sulfoxide  Oxidation  H2O2
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