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Synthetic studies toward swinhoeisterol A,a novel steroid with an unusual carbon skeleton
Authors:Atsuhiro Takano  Yiwen Zhao  Takayuki Ohyoshi  Hideo Kigoshi
Institution:Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba 305-8571, Japan
Abstract:Swinhoeisterol A is a novel steroid with unusual 6/6/5/7 tetracyclic skeleton. The model compound with BCD rings is constructed by Friedel–Crafts acylation and an oxidative dearomatization as key steps.
Keywords:Swinhoeisterol A  Steroid  6/65/7
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