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Palladium(O)-catalyzed allylic alkylation and amination of allylic phosphates |
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| Authors: | Yoshio Tanigawa Kazuaki Nishimura Akihiko Kawasaki Shun-Ichi Murahashi |
| Institution: | Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka 560, Japan |
| Abstract: | Allyl diethyl phosphates (1) can be easily substituted with malonates and amines in the presence of palladium(O) catalyst. Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate (1b) with high regio- and stereoselectivity. |
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