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Triflic acid promoted synthesis of polycyclic aromatic compounds
Authors:Ang Li
Institution:Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115, United States
Abstract:The triflic acid (CF3SO3H) promoted cyclizations of 2-styrylbiaryls are found to be useful for the synthesis of polycyclic aromatic compounds, including functionalized derivatives of polycyclic aromatic compounds and heterocyclic systems. The reaction involves cationic cyclization followed by an elimination of benzene from the intermediate product.
Keywords:Superacid  Arenes  Heterocycles  Cyclization
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