Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement |
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| Authors: | Gen-ichi Tsuchihashi Katsuhiko Tomooka Keisuke Suzuki |
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| Institution: | Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Kohoku-ku, Yokohama 223, Japan |
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| Abstract: | Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCl promoted pinacol-type rearrangement of chiral β-mesyloxy alcohols to give optically pure α-alkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant. |
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