Hydrometallation of 1-alkyl-3-trifluoromethyl propargyl alcohols |
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| Authors: | Yuji Hanzawa Kei-ichi Kawagoe Naomi Tanahashi Yoshiro Kobayashi |
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| Institution: | Tokyo College of Pharmacy, Horinouchi, Hachioji, Tokyo 192-03, Japan |
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| Abstract: | The hydrometallation of trifluoromethylated propargyl alcohol derivatives with metal hydride reagents proceeds smoothly to give cis- and trans-olefins on H2O quenching. The halodemetallation of intermediate formed in the reaction process was also examined. |
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