Palladium-catalyzed addition of hydroxylamine derivatives to Baylis-Hillman acetate adducts |
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| Authors: | Ch Raji Reddy N Kiranmai G Dattatreya Sarma S Chandrasekhar |
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| Institution: | a Organic Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
b Nuclear Magnetic Resonance Division, Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | The first use of hydroxylamine derivatives as the aminoxy equivalent of nucleophiles in palladium catalyzed addition to Baylis-Hillman acetate adducts is described. The reaction proceeds smoothly to give the substituted allyloxy amines in good yield and selectivity. |
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| Keywords: | Palladium Baylis-Hillman adduct Hydroxylamines |
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