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Nonlinear frequency response analysis: a recent review and perspectives
Authors:Tanja Vidakovi?-Koch  Tamara Mili?i?  Luka A ?ivkovi?  Hoon Seng Chan  Ulrike Krewer  Menka Petkovska
Institution:1. Max Planck Institute for Dynamics of Complex Technical Systems, Electrochemical Energy Conversion, Magdeburg, Germany;2. Karlsruhe Institute of Technology, Institute for Applied Materials – Electrochemical Technologies, Karlsruhe, Germany;3. University of Belgrade, Faculty of Technology and Metallurgy, Belgrade, Serbia
Abstract:The nonlinear frequency response analysis (NFRA) can be seen as an extension of electrochemical impedance spectroscopy. NFRA gives a full and detailed representation of the system response and can establish a connection between model parameters and the experimentally observed phenomena. In this article, different theoretical NFRA approaches and the most recent application examples are discussed. A simple electrochemical example is used to showcase the benefits and disadvantages of analyzing the system response by using different approaches. In addition, it was shown how to extract experimental harmonic values and analyze them.
Keywords:Harmonic analysis  Diagnosis  Kinetics  MModel discrimination  Battery
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